From English Wikipedia @ Freddythechick
Chemical element with atomic number 62 (Sm)
Samarium, 62 Sm Pronunciation (sə-MAIR -ee-əm ) Appearance silvery white
Atomic number (Z ) 62 Group f-block groups (no number)Period period 6 Block f-block Electron configuration [Xe ] 4f6 6s2 Electrons per shell 2, 8, 18, 24, 8, 2 Phase at STP solid Melting point 1345 K (1072 °C, 1962 °F) Boiling point 2173 K (1900 °C, 3452 °F) Density (at 20° C) 7.518 g/cm3 [3] when liquid (at m.p. ) 7.16 g/cm3 Heat of fusion 8.62 kJ/mol Heat of vaporization 192 kJ/mol Molar heat capacity 29.54 J/(mol·K) Vapor pressure
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
1001
1106
1240
(1421)
(1675)
(2061)
Oxidation states 0,[4] +1,[5] +2, +3 (a mildly basic oxide) Electronegativity Pauling scale: 1.17 Ionization energies 1st: 544.5 kJ/mol 2nd: 1070 kJ/mol 3rd: 2260 kJ/mol Atomic radius empirical: 180 pm Covalent radius 198± 8 pm Spectral lines of samariumNatural occurrence primordial Crystal structure rhombohedral (hR3 ) Lattice constants a r = 0.89834 nm α = 23.307°a h = 0.36291 nmc h = 2.6207 nm (at 20 °C)[3] Thermal expansion poly: 12.7 (at r.t. ) µm/(m⋅K) Thermal conductivity 13.3 W/(m⋅K) Electrical resistivity α, poly: 0.940 (at r.t. ) µΩ⋅m Magnetic ordering paramagnetic [6] Molar magnetic susceptibility +1860 .0× 10−6 cm3 /mol (291 K)[7] Young's modulus 49.7 GPa Shear modulus 19.5 GPa Bulk modulus 37.8 GPa Speed of sound thin rod 2130 m/s (at 20 °C) Poisson ratio 0.274 Vickers hardness 410–440 MPa Brinell hardness 440–600 MPa CAS Number 7440-19-9 Naming after the mineral samarskite (itself named after Vassili Samarsky-Bykhovets ) Discovery and first isolationLecoq de Boisbaudran (1879)
Category: Samarium | references
child table, as reused in {IB-Sm}
References
These references will appear in the article, but this list appears only on this page.
^ "Standard Atomic Weights: Samarium" . CIAAW . 2005.
^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)" . Pure and Applied Chemistry . doi :10.1515/pac-2019-0603 . ISSN 1365-3075 .
^ 3.0 3.1 Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements . Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9 .
^ Yttrium and all lanthanides except Ce and Pm have been observed in the oxidation state 0 in bis(1,3,5-tri-t-butylbenzene) complexes, see Cloke, F. Geoffrey N. (1993). "Zero Oxidation State Compounds of Scandium, Yttrium, and the Lanthanides". Chem. Soc. Rev . 22 : 17–24. doi :10.1039/CS9932200017 . and Arnold, Polly L.; Petrukhina, Marina A.; Bochenkov, Vladimir E.; Shabatina, Tatyana I.; Zagorskii, Vyacheslav V.; Cloke (2003-12-15). "Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation". Journal of Organometallic Chemistry . 688 (1–2): 49–55. doi :10.1016/j.jorganchem.2003.08.028 .
^ SmB6 - cluster anion has been reported and contains Sm in rare oxidation state of +1; see Paul, J. Robinson; Xinxing, Zhang; Tyrel, McQueen; Kit, H. Bowen; Anastassia, N. Alexandrova (2017). "SmB6 – Cluster Anion: Covalency Involving f Orbitals" . J. Phys. Chem. A 2017, 121, 8, 1849–1854 . 121 (8): 1849–1854. doi :10.1021/acs.jpca.7b00247 . PMID 28182423 . S2CID 3723987 . .
^ Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. p. 4-134. ISBN 0-8493-0486-5 .
^ Weast, Robert (1983). CRC, Handbook of Chemistry and Physics . Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E112. ISBN 978-0-8493-0464-4 .
^ 8.0 8.1 Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF) . Chinese Physics C . 45 (3): 030001. doi :10.1088/1674-1137/abddae .
^ 9.0 9.1 Chiera, Nadine M.; Sprung, Peter; Amelin, Yuri; Dressler, Rugard; Schumann, Dorothea; Talip, Zeynep (1 August 2024). "The 146 Sm half-life re-measured: consolidating the chronometer for events in the early Solar System" . Scientific Reports . 14 (1). doi :10.1038/s41598-024-64104-6 . PMC 11294585 .
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