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Chemical element with atomic number 45 (Rh)
Rhodium, 45 Rh Pronunciation (ROH -dee-əm ) Appearance Silvery white metallic
Atomic number (Z ) 45 Group group 9 Period period 5 Block d-block Electron configuration [Kr ] 4d8 5s1 Electrons per shell 2, 8, 18, 16, 1 Phase at STP solid Melting point 2237 K (1964 °C, 3567 °F) Boiling point 3968 K (3695 °C, 6683 °F) Density (at 20° C) 12.423 g/cm3 [3] when liquid (at m.p. ) 10.7 g/cm3 Heat of fusion 26.59 kJ/mol Heat of vaporization 493 kJ/mol Molar heat capacity 24.98 J/(mol·K) Vapor pressure
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
2288
2496
2749
3063
3405
3997
Oxidation states −3[4] , −1, 0, +1, +2, +3 , +4, +5, +6, +7[5] (an amphoteric oxide) Electronegativity Pauling scale: 2.28 Ionization energies 1st: 719.7 kJ/mol 2nd: 1740 kJ/mol 3rd: 2997 kJ/mol Atomic radius empirical: 134 pm Covalent radius 142±7 pm Spectral lines of rhodiumNatural occurrence primordial Crystal structure face-centered cubic (fcc) (cF4 ) Lattice constant a = 380.34 pm (at 20 °C)[3] Thermal expansion 8.46× 10−6 /K (at 20 °C)[3] Thermal conductivity 150 W/(m⋅K) Electrical resistivity 43.3 nΩ⋅m (at 0 °C) Magnetic ordering paramagnetic [6] Molar magnetic susceptibility +111.0× 10−6 cm3 /mol (298 K)[7] Young's modulus 380 GPa Shear modulus 150 GPa Bulk modulus 275 GPa Speed of sound thin rod 4700 m/s (at 20 °C) Poisson ratio 0.26 Mohs hardness 6.0 Vickers hardness 1100–8000 MPa Brinell hardness 980–1350 MPa CAS Number 7440-16-6 Discovery and first isolationWilliam Hyde Wollaston (1804)
Category: Rhodium | references
child table, as reused in {IB-Rh}
References
These references will appear in the article, but this list appears only on this page.
^ "Standard Atomic Weights: Rhodium" . CIAAW . 2017.
^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)" . Pure and Applied Chemistry . doi :10.1515/pac-2019-0603 . ISSN 1365-3075 .
^ 3.0 3.1 3.2 Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements . Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9 .
^ Ellis J E. Highly Reduced Metal Carbonyl Anions: Synthesis, Characterization, and Chemical Properties. Adv. Organomet. Chem, 1990, 31: 1-51.
^ Rh(VII) is known in the RhO3 + cation, see Da Silva Santos, Mayara; Stüker, Tony; Flach, Max; Ablyasova, Olesya S.; Timm, Martin; von Issendorff, Bernd; Hirsch, Konstantin; Zamudio‐Bayer, Vicente; Riedel, Sebastian; Lau, J. Tobias (2022). "The Highest Oxidation State of Rhodium: Rhodium(VII) in [RhO3]+" . Angew. Chem. Int. Ed . 61 (38): e202207688. doi :10.1002/anie.202207688 . PMC 9544489 . PMID 35818987 .
^ Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5 .
^ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics . Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4 .
^ 8.0 8.1 Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF) . Chinese Physics C . 45 (3): 030001. doi :10.1088/1674-1137/abddae .
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